2 research outputs found
Density functional theory study of the nematic-isotropic transition in an hybrid cell
We have employed the Density Functional Theory formalism to investigate the
nematic-isotropic capillary transitions of a nematogen confined by walls that
favor antagonist orientations to the liquid crystal molecules (hybrid cell). We
analyse the behavior of the capillary transition as a function of the
fluid-substrate interactions and the pore width. In addition to the usual
capillary transition between isotropic-like to nematic-like states, we find
that this transition can be suppressed when one substrate is wet by the
isotropic phase and the other by the nematic phase. Under this condition the
system presents interface-like states which allow to continuously transform the
nematic-like phase to the isotropic-like phase without undergoing a phase
transition. Two different mechanisms for the disappearance of the capillary
transition are identified. When the director of the nematic-like state is
homogeneously planar-anchored with respect to the substrates, the capillary
transition ends up in a critical point. This scenario is analogous to the
observed in Ising models when confined in slit pores with opposing surface
fields which have critical wetting transitions. When the nematic-like state has
a linearly distorted director field, the capillary transition continuously
transforms in a transition between two nematic-like states.Comment: 31 pages, 10 figures, submitted to J. Chem. Phy
Variscan Metamorphism
Various segments of Variscan crust are currently exposed in Iberia in response to successive tectonic events during the Variscan orogeny itself and subsequent extensional and compressive events during the Alpine cycle, all accompanied by surface erosion, and collectively contributing to their exhumation. We review the main characteristics and geodynamic contexts of the metamorphic complexes developed in Iberia during the Variscan cycle, which include: (i) LP-HT complexes associated to the Cambrian-Early Ordovician rift stage; (ii) HP-LT complexes associated to subduction; and (iii) syn-to-post-collisional, MP and LP/HT complexes from the hinterland to the foreland fold-and thrust belts. All the above contexts are illustrated with case studies. Finally, a review of Variscan metamorphism in the Pyrenees and Catalan Coastal Ranges, located far away from the Rheic suture is also presented